Definition

From Bond cleavage. In a homolytic bond cleavage, the bonding pair of electrons is split evenly between the products. The cleaving generates two uncharged product species or radicals, each of which bears an unpaired electron.

Example

Generalization

Structural reaction scheme for Homolitic Bond Cleavage, diagram 1 of 2
Figure 1. Homolitic Bond Cleavage

Eg: The chain initiation step in monochlorination of methane

Structural reaction scheme for Homolitic Bond Cleavage, diagram 2 of 2
Figure 2. Homolitic Bond Cleavage