Definition

An sp hybridized orbital is an atomic orbital achieved by the interference of one s orbital with one p orbitals. This gives rise to two degenerate hybridized atomic orbitals.

Explanation

Example – Triple bonded hydrocarbon molecules

As compared to sp3 and sp2 hybridization, sp hybridization helps us understand the structure of triple-bonded hydrocarbons like ethyne, propyne, etc. In this case, the carbon atom is bonded to only 2 other atoms. Therefore, one s orbital interacts with one p orbitals, to form 2 degenerate sp hybridized orbitals.

Orbital diagram for carbon in triple bonded molecules:-

Structural reaction scheme for Sp-Hybridized Orbitals, diagram 1 of 2
Figure 1. Sp-Hybridized Orbitals

Ethyne molecule –

Structural reaction scheme for Sp-Hybridized Orbitals, diagram 2 of 2
Figure 2. Sp-Hybridized Orbitals