Free radical bromination [hν, Br2]
Free Radical Bromination of Alkanes Definition:
When treated with bromine (Br2) and light (hν) alkanes are converted into alkyl bromides. Bromination of tertiary carbons is selective when in absence of any double bonds.
Free Radical Bromination of Alkanes Explained:
Initiation: Creation of radicals – When bromine (Br2) treated with light (hν) it comes to homolytic cleavage of the Br-Br bond.
Propagation: This stage consists of two steps
- A bromine atom attacks 2-methyl propane by abstracting hydrogen atom with which they form a hydrogen bromide and a tert-butyl radical.
- A tert-butyl radical abstracts a bromide atom from one of the starting Br2 molecules and new bromide atom react with a new molecule of starting substance in propagation step
And in a very small yield:
Propagation step 1:
Propagation step 2:
Termination: Recombination of every two radicals