Aromatic Compounds

13 reactions in this topic, each with the reagents, the mechanism and the structure of the product.

Bromination [Br2 plus catalyst]

Treatment with an aromatic such as benzene with bromine (Br2) and a Lewis acid (such as AlCl3 or FeCl3) leads to formation the bro

Chlorination [Cl2 plus catalyst]

Treatment of an aromatic (such as benzene) with chlorine (Cl2) and a Lewis base such as AlCl3 or FeCl3 leads to the formation of t

Chlorohydrin formation [Cl2/H2O]

The chlorohydrin formation reaction involves adding chlorine and water to a double bond and creating a chlorohydrin (chloro=chlori

Iodination [I2/catalyst]

Treatment of an aromatic such as benzene with iodine (I2) and copper (II) leads to the formation of the iodinated benzene by elect

Nitration [HNO3/H2SO4]

Aromatic groups can be nitrated by the action of nitric acid and an acid catalyst in the reaction of electrophilic aromatic substi

Reduction of aromatic ketones

When treated with a metal catalyst such as palladium (Pd) or platinum (Pt) and hydrogen gas (H2) ketones next to aromatic groups a

Reduction of nitro groups

Nitro groups can be converted into amino groups by treatment with reducing agents such as palladium on carbon with hydrogen (Pd/C,

Side chain bromination

When treated with N-bromosuccinimide (NBS) and light (hν) alkyl group adjacent to aromatic groups will be converted to into alkyl

Sulfonylation [SO3/H2SO4]

Treatment of an aromatic molecule such as benzene with sulfur trioxide and strong acid leads to the formation of sulfonic acid in